Method of using polyvinypolypyrrolidone to remove contaminants from produced water of an oil or gas well

ABSTRACT

A method of removing contaminants from produced water of an oil or gas well comprising the step of contacting the produced water with polyvinylpolypyrrolidone (PVPP) to remove the contaminants from the water.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of application Ser. No. 12/280,165filed Sep. 9, 2008, which is the National Stage of InternationalApplication No. PCT/US2007/004725 filed Feb. 23, 2007, which claims thebenefit of U.S. Provisional Application No. 60/776,766 filed Feb. 24,2006, the contents of these documents are hereby incorporated byreference.

FIELD OF THE INVENTION

The present invention relates to a method for removing contaminants fromproduced water of an oil or gas well.

BACKGROUND OF THE INVENTION

Oil and gas wells frequently produce a mixed stream of gas, liquidhydrocarbons and water. The mixed stream flows or is pumped to thesurface and separated using conventional separating systems. Afterrecovery of the oil and/or gas, the produced water often is reinjectedinto a disposal well or otherwise recycled or disposed of.

Concerns over possible contamination of the water supply through thepresence of oil and other contaminants in the produced water has risendramatically in recent years. The produced water may containcontaminants such as, for example, difficult to remove aromatics such asbenzene, xylene, toluene, phenols and polyphenols. Many governmentalauthorities require such contaminants to be removed from the producedwater before reinjection into a disposal well or other disposition. Thelevel of contamination permitted by government regulation varies. Insome older wells recovered oil may be 10% or less of a well's totaloutput and produced water 90% or higher, making it particularlydifficult to remove these contaminants from the produced water.

What is needed is a simple economical method for removing contaminantsform the produced water.

SUMMARY OF THE INVENTION

We have discovered a simple economical method for removing aromaticand/or acid contaminants such as benzene, xylene, toluene, phenols andpolyphenols from the produced water of an oil or gas well. In accordancewith the invention, there is provided a method of removing contaminantsfrom produced water of an oil or gas well comprising the step ofcontacting the produced water with polyvinylpolypyrrolidone (PVPP) toremove the contaminants from the water.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

While the invention herein is described with particular reference to apreferred embodiment, i.e., for removing aromatic acidic contaminantsfrom the produced water of an oil or gas well, it also finds utility inother applications where water and hydrocarbons are being separated andit is desired to reduce the level of contamination in the water.

According to the invention, aromatic and acid contaminants in theproduced water of an oil or gas well are removed by contacting theproduced water with polyvinylpolypyrrolidone (PVPP). PVPP, also known ascrosslinked poly(N-vinylpyrrolidone), is a crosslinked polymercontaining repeating units of the formula:

Any suitable crosslinker can be used. The particular crosslinkerselected is not believed to be critical to the practice of theinvention.

PVPP is known to be a highly effective stabilizer for beer. In the caseof beer, non-biological haze formation results primarily from thehydrogen bonding between haze producing proteins and the polyphenolconstituents of beer. Colloidal stability is achieved by reducing and/orpreventing the formation of polyphenol/protein complexes. PVPP isbelieved to complex with specific polyphenols in beer via hydrogenbonding and can be removed during subsequent filtration.

Suitable for use in the present invention is PVPP that is known to beuseful in stabilizing beer. Such PVPP includes POLYCLAR® 10 andPOLYCLAR® SUPER R, both commercially available from InternationalSpecialty Products. POLYCLAR® 10 is available as a water insoluble whitepowder comprising particles having an average size of about 25 microns.POLYCLAR® SUPER R is available as a water insoluble white powdercomprising particles having an average size of about 110 microns. Alsosuitable for use in the present invention is a fine grade PVPPcommercially available from International Specialty Products under thetrade name ViviPrint PS-10 having an average particle size of about 15microns. The PVPP can also take the form of particles, includingnano-size particles dispersed in polyvinylpyrrolidone. Such compositionscan be prepared as described in U.S. Pat. No. 6,548,597, the disclosureof which is hereby incorporated by reference in its entirety, and arecommercially available as a viscous liquid (10-12% solids) fromInternational Specialty Products under the trade name ViviPrint 540.

The PVPP can be added as a dry powder or more preferably as a slurry tothe produced water either directly, via cross-flow or in a contactvessel. The slurry can be prepared in either hot or cold water. Optimalcontact between the PVPP and the contaminated water can be achieved byproportional dosing of the PVPP into the produced water flow or contactvessel. The preferred dosing rate depends, of course, upon thecharacteristics of the produced water, and, in particular, thecomposition and concentration of the contaminants. After contact, thePVPP can be separated from the produced water. This can be accomplishedby conventional means for separating particles from water includingconventional filtration devices.

While applicants do not wish to be bound by any theories, it is believedthat acidic or aromatic contaminants such as benzene, xylene, toluene,phenols and polyphenols that inherently exist in produced waters fromoil and gas wells form complexes with the PVPP via pi bonds with thenitrogen-containing rings of the PVPP. The large surface area of thewater insoluble PVPP particles provides effective complex formation and,consequently, effective contaminant removal.

While a preferred embodiment of the invention has been described forillustrative purposes, it should be understood that many changes,substitutions and modifications will be readily apparent to thoseskilled in the art in light of the foregoing disclosure withoutdeparting from the scope and spirit of the present invention which isdefined by the claims which follow.

What is claimed is:
 1. A method of removing contaminants from producedwater of an oil or gas well comprising the step of contacting saidproduced water with polyvinylpolypyrrolidone (PVPP) to remove saidcontaminants from said water.
 2. The method of claim 1 wherein saidcontaminant is selected from the group consisting of benzene, xylene,toluene, phenols and polyphenols.
 3. The method of claim 1 wherein saidPVPP is in the form of a water insoluble powder comprising particleshaving an average size of about 110 microns.
 4. The method of claim 1wherein said PVPP is in the form of a water insoluble powder comprisingparticles having an average size of about 25 microns.
 5. The method ofclaim 1 wherein said PVPP is in the form of a water insoluble powdercomprising particles having an average size of about 15 microns.
 6. Themethod of claim 1 wherein said PVPP is in the form of particlesdispersed in polyvinylpyrrolidone.
 7. The method of claim 1 furthercomprising the step of separating said PVPP from said produced water.